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Today 38, 157- I 62. Karge, H. (1997) Post synthesis modification of microporous materials by solidstate reactions, in Progress in Zeolite and Microporous Materials, Studies in Surf. Sci. , Amsterdam, pp. 1901-1948. Li, Y. and Armor, J. N. (1999) Ammoxidation of ethane to acetonitrile. V. Solid state ion exchange to prepare cobalt zeolite catalysts, Appl. Catat, A: General 188, 211-217. 29 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. , Doan, P. and Sachtler, W. M. H. (2000) Coordination of C0 2+ cations inside cavities of zeolite MFI with lattice oxygen and adsorbed ligands, J.

Thus, the Co-zeolite might exhibit rather variable structures of the Co ion species, and generally substantial rearrangement within this material can take place. This is the reason why studies from various laboratories frequently report different results for apparently identical samples. Finally, it is necessary to stress that the Co ions, and TMI in general, in zeolite matrices, behave differently in different reactions. ). (ii) The highest yields in ammoxidation of ethane to acetonitrile on Co-zeolites are reported with Co-BEA zeolite, followed by Co-MFI, while the Co ions in FER are inactive (6).

Mizuno, N. 1. Decomposition on excessively copper ion exchanged ZSM-S zeolites, l Phys. Chern. 95, 3727-3730. 2. , and Yahiro, H. (1994) Novel catalytic decomposition and reduction of NO, Catal. Today 22, S-18. 3. Li, Y. and Armor, IN. (1994) Selective reduction of NOx by methane on Co-ferrierites. I. Reaction and kinetic-studies, l Catal. 150,376-387. 4. L. and Armor, IN. (1994) Selective reduction of NOx by methane on Co-ferrierites. II. Catalyst characterization, l Catal. 150,388-399. S. Li, Y.

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Ado’s theorem by Andrew Phillips


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